Background
Type:

{2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)-bis(phenylmethylidyne) ]-diphenolato}nickel(II)

Journal: Acta Crystallographica Section E: Structure Reports Online (16005368)Year: September 2011Volume: 67Issue:
Kargar H. Kia R.Moghadam M.a Froozandeh F. Tahir M.N.
a :University of Isfahan - IRAN(IR) - Isfahan
Green • GoldDOI:10.1107/S1600536811029813Language: English

Abstract

The asymmetric unit of the title complex, [Ni(C 31H 28N 2O 2)], comprises two crystallographically independent molecules. The geometry around the Ni II atom in each molecule is distorted square planar. The dihedral angles between the two phenoxy rings in each molecule are 17.8 (4) and 36.5 (4)°. The crystal packing is stabilized by weak π-π interactions [centroidcentroid distance = 3.758 (5) Å] and C - H⋯π interactions.