Type:
1-[((E)-{2-[(2-Nitrobenzyl)(2-{[(E)-(2-oxidonaphthalen-1-yl)methylidene] azaniumyl}ethyl)amino]ethyl}azaniumylidene)methyl]naphthalen-2-olate monohydrate
Journal: Acta Crystallographica Section E: Structure Reports Online (16005368)Year: December 2011Volume: 67Issue:
Abstract
The title Schiff base compound, C33H30N 4O4·H2O, adopts an E configuration with respect to each C=N double bond. In the molecule, there are naphthoxide anions and the protonated imino N atoms. intramolecular N-H⋯O hydrogen bonds lead to the formation of approximately planar (maximum deviation 0.029 Å for H atom) six-membered rings.. In the crystal, molecules are linked by O-H⋯O and N-H⋯O hydrogen bonds as well as C - H⋯O contacts, leading to the formation of a three-dimensional network..
Author Keywords
data-to-parameter ratio = 13.3mean σ(C-C) = 0.004 ÅR factor = 0.058single-crystal X-ray studyT = 296 KwR factor = 0.195