New 2D polyoxoanions built up of A-type sandwich anions and trivalent cerium, neodymium and samarium cations

Abstract

New 2D undulating layer pure inorganic polymers H2[{M(H2O)8 M(H2O)7M(H2O)6}P2W18Ce3O70(OH)(H2O)2] xH2O; M = Ce3+ (1), Nd3+ (2) and Sm3+ (3) were synthesized by routine synthetic reactions in aqueous solution and characterized by elemental analysis, IR spectra, cyclic voltammetry, XRPD, magnetic susceptibility, TG analysis, and X-ray single-crystal diffraction. The 2D framework of 1-3 were built by tri-Ce4+ substituted sandwich-type polyoxoanions modified by six trivalent lanthanide cations M(H2O)x (x = 6-8) units. The M(H2O)x (x = 6-7) groups act as bridges to form 2D undulating layer, but the M(H2O)8 groups link the 2D layers together via hydrogen bonds to form a 3D supra-molecular framework. © 2015 Iranian Chemical Society.