Type:
[(Z)-1-({3-[(3-Aminopropyl)(2-nitrobenzyl)amino]propyl}iminomethyl) -naphthalen-2-olato]copper(II) perchlorate
Journal: Acta Crystallographica Section E: Structure Reports Online (16005368)Year: December 2011Volume: 67Issue:
Abstract
In the title compound, [Cu(C24H27N4O 3)]ClO4, the CuII atom has a distorted square-planar coordination geometry and is surrounded by an N3O donor set composed of a secondary amine N, a primary amine H, an imino N and a naphthalen-2-olate O atom. An intramolecular N - H⋯O hydrogen bond occurs. In the crystal, molecules are held together by intermolecular N-H⋯O hydrogen bonds, leading to the formation of a three-dimensional network.
Author Keywords
data-to-parameter ratio = 15.7mean σ(C-C) = 0.004 ÅR factor = 0.039single-crystal X-ray studyT = 296 KwR factor = 0.117