Background
Type: Article

A Facile, Mild, and Environmentally Benign Procedure for the Cleavage of Carbon-Nitrogen Double Bonds Using KMnO4 in the Presence of Montmorillonite K-10 under Solvent-Free Conditions

Journal: Monatshefte fur Chemie (00269247)Year: 2003/04/01Volume: Issue: 4
Mohammadpoor Baltork I.a Khodaei M.M. Hajipour A.R. Aslani E.
DOI:10.1007/s00706-002-0556-xLanguage: English

Abstract

An efficient and environmentally benign method for the conversion of oximes, semicarbazones, phenylhydrazones, and azines to their corresponding carbonyl compounds using KMnO4/montmorillonite K-10 as a commercially available, non-toxic, stable, and inexpensive reagent is reported.


Author Keywords

AzinesMontmorillonite K-10OximesPhenylhydrazonesSemicarbazonescarboncarbonyl derivativemanganese derivativemontmorillonitenitrogenoxideoxime derivativephenylhydrazone derivativepotassium derivativereagentsemicarbazone derivativesolvent