Background
Type: Article

Benzyltriphenylphosphonium peroxodisulfate (PhCH2PPh 3)2S2O8: An efficient and convenient reagent for the oxidative cleavage of phenylhydrazones, paranitrophenylhydrazones, and semicarbazones to their parent carbonyl compounds

Journal: Phosphorus, Sulfur and Silicon and the Related Elements (10426507)Year: 2003/12/01Volume: Issue: 12
Tajbakhsh M.Mohammadpoor Baltork I.a Ramzanian-Lehmali F.
DOI:10.1080/714040975Language: English

Abstract

Deprotection of phenylhydrazones, paranitrophenylhydrazones, and semicarbazones to their parent aldehydes and ketones in high yields has been carried out using benzyltriphenylphosphonium peroxodisulfate as a selective oxidant under mild conditions.