Background
Type: Article

{4,4′-Dichloro-2,2′-[2,2-dimethyl-propane-1, 3-diylbis(nitrilo-methanylyl-idene)]diphenolato}copper(II)

Journal: Acta Crystallographica Section E: Structure Reports Online (16005368)Year: 2012/08/01Volume: Issue: 8
Kargar H. Kia R.Ganji F.Mirkhani V.a
Green • GoldDOI:10.1107/S1600536812033491Language: English

Abstract

In the title Schiff base complex, [Cu(C19H18Cl2N2O2)], the CuII ion is coordinated in a distorted square-planar environment by two N atoms and two O atoms of the tetra-dentate ligand. The dihedral angle between the benzene rings is 36.86 (14)°. In the crystal, mol-ecules are linked into inversion dimers by pairs of weak C-H⋯O hydrogen bonds. In addition, π-π [centroid-centroid distance = 3.7279 (16) Å] and weak C-H⋯π inter-actions are observed.


Author Keywords

data-to-parameter ratio = 18.2mean σ(C-C) = 0.004 ÅR factor = 0.042single-crystal X-ray studyT = 296 KwR factor = 0.098Tetra