Background
Type: Article

Ferric nitrate/molibdatophosphoric acid as a new and efficient system in the oxidative deprotection of trimethylsilyl ethers to corresponding carbonyl compounds under solvent-free conditions

Journal: Journal of the Chinese Chemical Society (00094536)Year: 2006/06/01Volume: Issue: 3
Zolfigol M.A.Mohammadpoor Baltork I.aShiri M.
DOI:10.1002/jccs.200600071Language: English

Abstract

Oxidative deprotection of a variety of trimethylsilyl ethers were performed by Fe(NO3)3·9H2O in the presence of H3PMo12O40·xH2O as catalyst at room temperature in good to high yields under solvent-free conditions.


Author Keywords

Carbonyl compoundsFerric nitrate nona hydrateHeteropolyacidsMolibdatophosphoric acidTrimethylsilyl ethers