Background
Type: Article

N-(2-Ethoxyphenyl)formamide

Journal: Acta Crystallographica Section E: Structure Reports Online (16005368)Year: 2012/02/01Volume: 68Issue: 2
Rofouei, Mohammad KazemAttar Gharamaleki, JafarYounesian, Fereshteh Bruno G.Amiri Rudbari H.a
Green • GoldDOI:10.1107/S160053681200205XLanguage: English

Abstract

The title compound, C 9H 11NO 2, was obtained as an unexpected product in an attempt to synthesize a triazene ligand. The title mol-ecule is almost planar, with the formamide and eth-oxy groups oriented at 2.7 (3) and 12.9 (2)°, respectively, with respect to the mean plane of the benzene ring. In the crystal, mol-ecules are linked by inter-molecular N - H⋯O hydrogen bonds, forming a chain along the a axis. Weak C - H⋯π inter-actions with an H⋯π distance of 2.78 Å reinforce the crystal packing, resulting in a three-dimensional network.


Author Keywords

data-to-parameter ratio = 17.8mean σ(C-C) = 0.003 ÅR factor = 0.043single-crystal X-ray studyT = 296 KwR factor = 0.120