Type: Article

Efficient oxidative decarboxylation of carboxylic acids with sodium periodate catalyzed by supported manganese (III) porphyrin

Journal: Bioorganic and Medicinal Chemistry Letters (0960894X)Year: 2003/10/20Volume: Issue: 20

Mirkhani V.^aTangestaninejad S.^aMoghadam M.^a Karimian Z.

a :University of Isfahan - IRAN(IR) - Isfahan

DOI:10.1016/S0960-894X(03)00749-2Language: English

Abstract

Oxidative decarboxylation of carboxylic acids by a supported manganese (III) porphyrin was investigated. In the chemical system using 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatomanganese (III) chloride supported on crosslinked chloromethylated polystyrene, [Mn(H 2NTPP)-CMP], as catalyst, carboxylic acids are converted to the corresponding carbonyl compounds via oxidative decarboxylation with sodium periodate. © 2003 Elsevier Ltd. All rights reserved.