Type: Article

Mild and efficient oxidation of alcohols with sodium periodate catalyzed by polystyrene-bound Mn(III)porphyrin

Journal: Bioorganic and Medicinal Chemistry (09680896)Year: 2005/04/15Volume: Issue: 8

Moghadam M.^aTangestaninejad S.^aMirkhani V.^aMohammadpoor Baltork I.^aKargar H.

a :University of Isfahan - IRAN(IR) - Isfahan

DOI:10.1016/j.bmc.2005.02.012Language: English

Abstract

Mild and efficient oxidation of primary and secondary alcohols with sodium periodate catalyzed by Mn(TPyP), [manganese(III)tetra(4-pyridyl)porphyrin], supported on chloromethylated polystyrene, [Mn(TPyP)-CMP], at room temperature were reported. This catalyst can be reused consecutively four times in the oxidation of 4-chlorobenzyl alcohol in 97% yield without significant loss of its activity. © 2005 Elsevier Ltd. All rights reserved.