Olefin epoxidation with tert-BuOOH catalyzed by vanadium polyoxometalate immobilized on ionic liquid-modified MCM-41

Abstract

Preparation and characterization of vanadium-containing polyphosphomolybdates supported on ionic liquid-modified MCM-41, MCM-41-Im, are reported. The catalyst, [PVMo@MCM- 41-Im], was characterized by elemental analysis, X-ray diffraction, scanning electron microscopy and also FT-IR, and UV-Vis spectroscopic methods. This heterogeneous catalytic system was applied for efficient epoxidation of various olefins in the presence of tert-BuOOH in 1,2-dichloroethane under reflux. The catalyst can be reused several times without apparent loss of its catalytic performance. © 2011 Taylor & Francis.