Synthesis of aqueous media stable MIL101-OH/chitosan for diphenhydramine and metronidazole adsorption

In this work, maximizing the utilization of CO2 and its precipitation as CaCO3 by using immobilized bovine carbonic anhydrase (BCA) was evaluated. In this way, selection of suitable carriers which have a gas adsorption function would enhance the CO2 sequestration efficiency of the carbonic anhydrase (CA). So a metal-organic framework (MOF), an excellent material for gas adsorption and enzyme immobilization was used. In this manner, BCA was encapsulated into the microporous zeolite imidazolate framework, ZIF-8, for the first time, using a bottle-Around-A-ship method. Systematic characterization including powder X-ray diffraction (PXRD), UV-vis, and Fourier transform infrared (FT-IR) spectroscopies, BET, field emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray (EDX) confirmed that the entrapment of BCA molecules was successfully achieved during the crystal growth of ZIF-8 with an enzyme loading of ca. 100 ± 1.2 mg g-1 of BCA-ZIF-8. Optimization of the matrix for increasing the stability of the enzyme in an encapsulated form is the main aim of the present study. The de novo approach was proposed because this method provides better enzyme protection from degradation, minimizes enzyme leaching and enables multiple reuse. Then, the influence of different parameters, including pH, temperature, storage and reusability, was evaluated for enzyme@MOF composites versus free enzymes. The prepared biocatalyst exhibited outstanding activity in a wide pH and temperature range and demonstrates high storage stability up to 37 days. This efficient and simple association procedure seems well-Adapted to produce an enzymatic bio-catalyst for biocatalytic hydration of CO2. The FT-IR analysis revealed that the structure of BCA was well maintained during the encapsulation process. The thermal stability and reusability of the BCA-ZIF-8 increased noticeably due to the structural rigidity and confinement of the ZIF-8 scaffolds. These two parameters are very important for practical applications. © 2019 The Royal Society of Chemistry.

Preparation and Application of a New Supported Nicotine-Based Organocatalyst for Synthesis of Various 1,5-Benzodiazepines

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Moeini korbekandi, M., Nasr-esfahani, M., Mohammadpoor baltork, I., Moghadam, M., Tangestaninejad, S., Mirkhani, V.

Publication Date: 2019

Catalysis Letters (1572879X)149(4)pp. 1057-1066

Synthesis of chiral palladium oxazolidine and imine complexes: Investigation the oxazolidine-imine conversion by DFT method

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Molaee, H., Moghadam, M., Mirkhani, V., Tangestaninejad, S., Mohammadpoor baltork, I., Abbasi kajani, A., Kia, R.

Publication Date: 2019

Polyhedron (02775387)160pp. 130-138

Task-Specific Ionic Liquid Functionalized-MIL-101(Cr) as a Heterogeneous and Efficient Catalyst for the Cycloaddition of CO 2 with Epoxides under Solvent Free Conditions

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Suzuki–Miyaura cross-coupling reaction by palladium immobilized on functionalized magnetic nanoparticles with NNN and NNS Schiff base ligands in a mild reaction condition

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Synthesis, characterization and separation of chiral and achiral diastereomers of Schiff base Pd(II) complex: A comparative study of their DNA- and HSA-binding

( Article . Green )

Kazemi, Z., Amiri rudbari, H., Sahihi, M., Mirkhani, V., Moghadam, M., Tangestaninejad, S., Mohammadpoor baltork, I., Azimi gandomani, G., Gharaghani, S., Abbasi kajani, A.

Publication Date: 2016

Journal of Photochemistry and Photobiology B: Biology (18732682)163pp. 246-260

Wheel-shaped copper containing polyoxotungstate as an efficient catalyst in the three-component synthesis of 1,2,3-triazoles

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( Article . Green )

Molecular Diversity (1573501X)16(4)pp. 727-735

The effect of encapsulated Zn-POM on the catalytic activity of MIL-101 in the oxidation of alkenes with hydrogen peroxide

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Canadian Journal of Chemistry (84042)(5)pp. 812-818

Tin(II) polyoxometalate as an efficient catalyst for the selective oxidation of sulfides to sulfoxides

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Titanium dioxide as a mild and efficient catalyst for conversion of epoxides to thiiranes

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( Article )

Tangestaninejad, S., Bordbar, A., Eslami A.

Publication Date: 2003

Polish Journal of Chemistry (1375083)(3)pp. 283-293

2002

Catalytic acetylation of alcohols and phenols with potassium dodecatungstocobaltate trihydrate

( Article . )

Habibi, M.H., Tangestaninejad, S., Mirkhani, V., Yadollahi, B.

Publication Date: 2002

Monatshefte fur Chemie (00269247)133(3)pp. 323-327

Cobalt polyoxometalate, CoW12O405- as a new reusable catalyst for the direct, fast, and efficient acetylation of alcohols and phenols under solventless conditions

( Article . )

Habibi, M.H., Tangestaninejad, S., Mirkhani, V., Yadollahi, B.

Publication Date: 2002

Synthetic Communications (00397911)32(6)pp. 863-867

Manganese porphyrin derivatives as ionophores for thiocyanate-selective electrodes: The influence of porphyrin substituents and additives on the response properties

( Article )

2000

Bismuth(III) chloride (BiCl3); an efficient catalyst for mild, regio- and stereoselective cleavage of epoxides with alcohols, acetic acid and water

( Article . )

Mohammadpoor baltork, I., Tangestaninejad, S., Aliyan, H., Mirkhani, V.

Publication Date: 2000

Synthetic Communications (00397911)30(13)pp. 2365-2374

Efficient and selective epoxidation of alkenes by supported manganese porphyrin under ultrasonic irradiation

( Article . )

Mirkhani, V., Tangestaninejad, S., Moghadam, M., Yadollahi, B.

Publication Date: 2000

Journal of Chemical Research - Part S (13645560)(11)pp. 515-517

Potentiometric detection of 2-mercaptobenzimidazole and 2-mercaptobenzothiazole at cobalt phthalocyanine modified carbon-paste electrode

( Article . )

Shahrokhian, S., Amini, M.K., Mohammadpoor baltork, I., Tangestaninejad, S.

Publication Date: 2000

Electroanalysis (10400397)12(11)pp. 863-867

Salicylate-selective electrodes based on Al(III) and Sn(IV) salophens

( Article )

آدرس

Ternary heterojunction Bi2WO6/TiO2/GO photocatalyst for the removal of Cefixime: Bridging experimental characterizations, photocatalytic reaction-informed neural network modeling, genetic algorithm optimization, and density functional theory computations

A multifaceted investigation on photocatalytic performance of Bi2WO6/TiO2/ZIF-8: Adsorption, artificial neural networks, density functional theory, and antibacterial assessment studies

Au nanoparticles decorated on sodium alginate biopolymer as a biocompatible platform for 6-mercaptopurine delivery

Covalent Immobilization of Lipase on NH2-MIL-125(Ti) through Ugi Reaction for Biodiesel Production

Dual-Function Heterogeneous Catalyst PMo11@MIL-101(Cr) for Efficient CO2Fixation and Sustainable Biodiesel Synthesis

Glucose oxidase immobilized on ZIF-7-III: composite formation, optimization and integration in an electrochemical biosensor for selective glucose detection

Highly efficient water desalination via electrospun ethyl cellulose/polystyrene composites integrated with metal-organic frameworks

Innovative cross-linked electrospun PVA/MOF nanocomposites for removal of cefixime antibiotic

Metal-organic frameworks-derived CaO/ZnO composites as stable catalysts for biodiesel production from soybean oil at room temperature

Oil well–produced water pollutant adsorption and photodegradation using an innovative double Z-scheme ternary heterostructure of MIL-101(Cr)/Fe3O4-SiO2/nanorod-graphitic carbon nitride: adsorption isotherm and degradation kinetic study

Photocatalytic removal of Cefixime using ZnO/ BiOBr/Bi2S3: Suspended and immobilized on Graphite

Shaping photocatalysis: How the morphology of a Ti-MOF dictates charge transport and efficiency in photoelectrochemical water splitting

Straightforward linker functionalization in UiO-66-NH2 via schiff-base condensation with metal acetylacetonate complex: A post-modification approach toward heterogeneous catalytic epoxidation

Surface-engineered chitosan-coated MIL-53(Fe) nanozyme with synergistic effect on peroxidase/oxidase mimic as a highly sensitive biosensor for the colorimetric detection of hydrogen peroxide

Synergistic Effect of Cold Plasma-Bimetallic Ni Co ZIF-67 as Breathable MOF System for Selective Hydrogenation of CO2 to Methanol

The catalyst-free green synthesis and QTAIM analysis of anilino-1,4-naphthoquinones as molecular wires

A pH-dependent and charge selective covalent organic framework for removal of dyes from aqueous solutions

Adsorption/photocatalytic degradation of Cefixime by the green Bi2WO6/g-C3N4/ZIF-67 dual S-scheme heterojunction: Artificial neural network, genetic algorithm, density functional theory, and toxicity assessments

Efficient synthesis of novel thiadiazolo[2,3-b]quinazolin-6-ones catalyzed by diphenhydramine hydrochloride-CoCl⋅6H2O deep eutectic solvent

Experimental and computational insights into the iodine vapor capture by imine-and amine-linked covalent organic frameworks

Investigation of structural, electronic, and optical properties of halide perovskites with different amide cations: A first-principles approach

Palladium-immobilized triazine dendrimer on magnetic nanoparticles: as reusable microreactor for solvent-dependent synthesis strategy of 2,3-diphenylindoles and pentaphenylpyrrole derivatives

Selective synthesis of thiadiazolo-2H-chromen-2-ones and chromeno-thiadiazolo-pyrimidines under thermal conditions and microwave irradiation catalyzed by calixarene-based ionic liquid immobilized on magnetic nanoparticles

Stability enhancement of perovskite solar cells using multifunctional inorganic materials with UV protective, self cleaning, and high wear resistance properties

Surface Engineering of Superparamagnetic Graphene Oxide Nanosheet as a Chemically Tunable Platform for Facial Biofuel Production by Lipase

Tuning structural change on lipase for covalently immobilization on S-decorated dendrimer: Efficient and reusable biocatalysts for biodiesel production

Waste carbon-based toner protection layer on CsPbBr3 perovskite photoanodes for efficient and stable photoelectrochemical water oxidation

A comprehensive comparison of green Bi2WO6/g-C3N4 and Bi2WO6/TiO2 S-scheme heterojunctions for photocatalytic adsorption/degradation of Cefixime: Artificial neural network, degradation pathway, and toxicity estimation

Adsorption and photocatalytic degradation of oilfield produced water by visible-light driven superhydrophobic composite of MIL-101(Cr)/Fe3O4-SiO2: Synthesis, characterization and optimization

Adsorption of cefixime and lamotrigine on HKUST-1/ZIF-8 nanocomposite: isotherms, kinetics models and mechanism

Arsenic Polyoxotungstate-Zeolitic Imidazolate Framework-8 as a Potential Selective Anti-cancer Nano Platform

Carbonic Anhydrase-Embedded ZIF-8 Electrospun PVA Fibers as an Excellent Biocatalyst Candidate

Diphenhydramine Hydrochloride-CuCl as a New Catalyst for the Synthesis of Tetrahydrocinnolin-5(1H)-ones

Effective photocatalytic degradation of amphotericin B and naproxen from aqueous solutions using carbon quantum dots combined in MIL-88B(Fe) under visible light.

Efficient photocatalytic performance of BiVO4/ ZIF-8 /Cu2S/Ag2S incorporated in solar driven-cleaning ABS/MWCNT membrane applied in metronidazole decontamination

Efficient tetracycline degradation and electricity production in photocatalytic fuel cell based on ZnO nanorod/BiOBr/UiO-66-NH2 photoanode and Cu2O/CuO photocathode

Fabrication of novel ZnO@BiOBr/UiO-66-NH2 core-shell heterojunction for improved tetracycline degradation

Green synthesize of nano-MOF-ethylcellulose composite fibers for efficient adsorption of Congo red from water

I ntegrated Electro-photo-Fenton process and visible light-driven TiO2/rGO/Fe2O3 photocatalyst based on graphite cathode in the presence of iron anode for Metronidazole degradation

Partially reduced-linked covalent organic frameworks: A new approach for heterogeneous catalysis and naked-eye HCl sensing

Self-healing perovskite solar cells based on copolymer-templated TiO2 electron transport layer

Synthesis and characterization of a new gold-coated magnetic nanoparticle decorated with a thiol-containing dendrimer for targeted drug delivery, hyperthermia treatment and enhancement of MRI contrast agent

Tetracycline removal from aqueous solution through photoelectrochemical oxidation process using Bi2O3/ZIF-67@GP under visible light irradiation: Effects of operational parameters, water matrix

The critical impacts of anion and cosolvent on morpholinium ionic liquid pretreatment for efficient renewable energy production from triticale straw

The enzymatic synthesis of lactose caprate using Candida rugosa lipase immobilized into ZIF-8 and investigation of its anticancer applications against K562 leukemia and HeLa cancer cells

Triazine diphosphonium tetrachloroferrate ionic liquid immobilized on functionalized halloysite nanotubes as an efficient and reusable catalyst for the synthesis of mono-, bis- and tris-benzothiazoles

3-(Propylthio)propane-1-sulfonic acid immobilized on functionalized magnetic nanoparticles as an efficient catalyst for one-pot synthesis of dihydrotetrazolo[1,5-a]pyrimidine and tetrahydrotetrazolo[5,1-b]quinazolinone derivatives

Adsorptive removal of ibuprofen to binary and amine-functionalized UiO-66 in the aquatic environment: synergistic/antagonistic evaluation

An efficient and selective olefination of aldehydes with ethyl diazoacetate using copper(II) bis-thiazole complex as heterogeneous catalyst

Copper-Curcumin-Bipyridine Dicarboxylate Complexes as Anticancer Candidates

Enhance performance ZnO/ Bi2MoO6/ MIL-101(Fe) grown on fluorine-doped tin oxide as photoanode and CuO/ Cu2O based on Cu mesh photocathode in the photocatalytic fuel cell

Hyaluronic acid targeted metal organic framework based on iron (III) for delivery of platinum curcumin cytotoxic agent to triple negative breast cancer cell line

Novel ZnO nanorods/Bi2MoO6/MIL-101(Fe) heterostructure immobilized on FTO with boosting photocatalytic activity for tetracycline degradation: Reaction mechanism and toxicity assessment

Preparation and characterization of stable core/ shell Fe3O4@Au decorated with an amine group for immobilization of lipase by covalent attachment

Synthesis and characterization of Bi2MoO6/MIL-101(Fe) as a novel composite with enhanced photocatalytic performance: Effect of water matrix and reaction mechanism

Synthesis and characterization of Bi2O3/ZIF-67 nanocomposite integration with capacitive deionization system in the degradation tetracycline

Synthesis of aqueous media stable MIL101-OH/chitosan for diphenhydramine and metronidazole adsorption

A novel Ru (II) complex with high absorbance coefficient: efficient sensitizer for dye-sensitized solar cells

Application of a new 4'-functionalized 2,2': 6',2''-terpyridine ruthenium(ii) complex as a sensitizer in dye sensitized solar cells

Copolymer-Templated Nickel Oxide for High-Efficiency Mesoscopic Perovskite Solar Cells in Inverted Architecture

Effect of immobilizing ionic liquid on amine-functionalized MIL-101(Cr) incorporated in Matrimid membranes for CO2/CH4 separation

Efficient colorful perovskite solar cells designed by 2D and 3D ordered titania inverse opals

Enhancement of CO2 adsorption on natural zeolite, modified clinoptilolite with cations, amines and ionic liquids

Investigation of copper plates as anode and TiO2/glycine/ZnFe2O4 stabilized on graphite as cathode for textile dyes degradation from aqueous solution under visible light

Multifunctional approach to improve water oxidation performance with MOF-based photoelectrodes

Photocatalytic degradation and adsorption of herbicide 2,4-dichlorophenoxyacetic acid from aqueous solution using TiO2/BiOBr/Bi2S3 nanostructure stabilized on the activated carbon under visible light

Preparation and characterization of nanofibrous metal-organic frameworks as efficient catalysts for the synthesis of cyclic carbonates in solvent-free conditions

Triazine bis(pyridinium) hydrogen sulfate ionic liquid immobillized on functionalized halloysite nanotubes as an efficient catalyst for one-pot synthesis of naphthopyranopyrimidines

Ce(IV) immobilized on halloysite nanotube–functionalized dendrimer (Ce(IV)–G2): A novel and efficient dendritic catalyst for the synthesis of pyrido[3,2-c]coumarin derivatives

Correction to: Efficient dye-sensitized solar cell based on a new porphyrin complex as an inorganic photosensitizer (Journal of Chemical Sciences, (2020), 132, 1, (75), 10.1007/s12039-020-01781-6)

Dynamic porous coordination polymers built-up from flexible 4,4′-dithiodibenzoate and rigid N-based ligands

Efficient dye-sensitized solar cell based on a new porphyrin complex as an inorganic photosensitizer

Excellent performance of a novel dual Z-scheme Cu2S/Ag2S/BiVO4 heterostructure in metronidazole degradation in batch and continuous systems: Immobilization of catalytic particles on α-Al2O3 fiber

Hierarchical Gold Mesoflowers in Enzyme Engineering: An Environmentally Friendly Strategy for the Enhanced Enzymatic Performance and Biodiesel Production

Hierarchical Ti-Based MOF with Embedded RuO2Nanoparticles: A Highly Efficient Photoelectrode for Visible Light Water Oxidation

Improved CO2 transport properties of Matrimid membranes by adding amine-functionalized PVDF and MIL-101(Cr)

Ionic Liquid Modification of Hierarchical ZSM-5 for Solvent-Free Insertion of CO2to Epoxides